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Biodiesel Production from Rubber Seed Oil via Esterification Process

Department of Chemical Engineering, Faculty of Engineering, Diponegoro University, Indonesia

Published: 1 Jul 2012.
Editor(s): H. Hadiyanto

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Abstract
One promise source of alternative energy is biodiesel from rubber seed oil, because the raw materials available in plentiful quantities and can be renewed. In addition, the rubber seed is still lack of utilization, and Indonesia is one of the largest rubbers producing country in the world. The objective of this research is to studied on biodiesel production by esterification process. Parameters used in this study are the ratio of catalyst and temperature and its influence on the characteristics of the resulting biodiesel product. Characterization of rubber seed include acid content number analysis, saponification numbers, density, viscosity, iodine number, type of free fatty acids and triglyceride oils. The results of analysis showed that rubber seed oil content obtained is 50.5%. The results of the GCMS analysis showed that a free fatty acid level in rubber seed is very high. Conversion into bio-diesel oil is obtained by at most 59.91% and lowest 48.24%.
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  1. Anonim, 2005, Buku Putih Program Pembangunan Iptek Bidang Ketersediaan Dan Pemanfaatan Sumber Energi Baru Dan Terbarukan 2005-2009
  2. Freedman, B.E.H.P., dan TL Mounts, 1984, "Variables affecting the yields of fatty ester from transesterified vegetable oils", JAOCS https://doi.org/10.1007/BF02541649
  3. Garpen, J.V., and Canakei M., 2000, " Biodiesel Production from Oils and Fats with High Free Fatty Acids", Am.Soc.Of Agricultural Eng., Vol. 44 : 1429-1436 https://doi.org/10.13031/2013.7010
  4. Hamilton, R.J. and Rossel, J.B., 1986., Analysis of Oils and Fats, 1st edition, Elsevier Applied Science Publisher Ltd.,
  5. Heyne, K, (1987), "Tumbuhan Berguna Indonesia II" , Badan Litbag Kehutanan, Jakarta, hal. 1186-1187
  6. Jackson, M.A., and King, J.W.,1996, "Methanolysis of seed oil in flowing supercritical carbondioxide", JAOCS 73, p.353-324 https://doi.org/10.1007/BF02523430
  7. Kalam, M.A., and Masjuki, H.H., (2002), "Biodiesel from palmoil-an analysis of itsproperties and potential," Biomass and Bioenergy 23 p.471-479 https://doi.org/10.1016/S0961-9534(02)00085-5
  8. Ketaren, S., 1986., Minyak dan Lemak Pangan, edisi 1, Penerbit Universitas Indonesia (UI Press),
  9. Korus A., dkk., "Transesterification process to manufacture etyl ester of rape oil", Proceedings of the first conference of the americas: energy, environment, agriculture and industry vol II, 1993, Burlington, USA
  10. Krawczyk, T. "Biodiesel-Alternative fuel makes inroad but hurdles remain", INFORM 7, 1996, p.801-829
  11. Ma, Fangrui, Clements, L.D., and Hanna, Milford A, (1999).,"Biodiesel Production: a review" Bioresource Technology 70 p.1-15 https://doi.org/10.1016/S0960-8524(99)00025-5
  12. Nelson, L.A., T.A. Foglia dan W.N. Marmer, 1996, Lipase-Catalyzed Production of Biodiesel. JAOCS, 73 (8) : 1191 - 1195
  13. https://doi.org/10.1007/BF02523383
  14. Othmer, K., Encyclopedia of Chemical Technology, 4th edition, Vol.10, John Wiley and Sons, New York, 1992
  15. Omata, F., A.C., Dimian dan A Bliek, 2003, "Fatty Acid esterification by reactive distillation", Chem Eng Sci, 58 page 3159-3174
  16. https://doi.org/10.1016/S0009-2509(03)00165-9
  17. Palupi, S dan D. D., Anggoro, 2007, "Transesterifikasi Minyak Biji Karet Dengan Katalis NaOH dan KOH", Prosiding Seminar Masyarakat Katalis Indonesia Society (MKICS), di Semarang, 18-19 April
  18. Paquout, C., 1979. Standard Methods for The Analysis of Fats and Derivatives, 6th edition, Pergamon Press, New York,
  19. Pioch, D., Lozano., P., Rasoanantoandro, M.C., Graille, J., Geneste, P., Guida, A.,1993, "Biofuels from catalytic cracking of tropical vegetable oils", Oleagineux 48, p.289-291
  20. Rasidi, "Kinetika Esterifikasi Asam Lemak Bebas dalam Minyak Sawit untuk pembuatan biodiesel", 2005, Seminar Nasional Teknik Kimia " Kejuangan" , UPN Veteran Yogyakarta
  21. Singh, A.P., J.C., Thompson dan B Brian He, 2004, ', A Continous-flow Reactive Distillation Reactor for Biodiesel Preparation from Seed Oils », Prosiding 2004 ASAE/CSAE Annual International Meeting », Ontaria, Canada, 1-4 Agustus
  22. Siirola, J.,J.,, 1995, "An Introduction perspective on process synthesis", AIChE Symposium Series No. 304 Vol. 91 pp 222 -233
  23. Towler, G.P. and Frey, S.J., 2000, "Reactive distillation" in S.Kulprathiapanja, Reactive separation processes, Philadelphia: taylor and francis (Chapter 2)
  24. Taylor, R. dan R. Krishna, 2000, "Modeling Reactive Distillation", Chemical Engineering Science, Pergamon. https://doi.org/10.1016/S0009-2509(00)00120-2
  25. Watanabe, Y, Y. Shimada, A. Sugihara dan Y Tominaga, 2001. Enzymatic Conversion of Waste Edible Oil to Biodiesel Fuel in a Fixed-Bed Bioreactor. JAOCS 78 (7) : 701 - 707. https://doi.org/10.1007/s11746-001-0329-5

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